Galician research on the application of laser technology in the cleaning of material cultural heritage: past and future strategies
Main Article Content
Abstract
The cleaning of cultural heritage elements is essential to ensure the durability and transmission of our cultural and artistic legacy. In Galicia, the importance of our stone-built heritage reflects the skill of our masters and artisans and is a symbol of our strength as a community. The difficulty involved in cleaning polymineralic stones such as granites, schists, etc. used on these artworks justifies the need to carry out detailed research on the effectiveness of different cleaning methods, considering both the degree of extraction of the undesirable substance (crust, graffiti, biological colonization, etc.) and the side effects that such cleaning may cause, such as mineral extraction, chromatic changes, etc. For this reason, a group of researchers from the University of Vigo and the University of A Coruña have been working together for 13 years to optimize the application of laser technology as a cleaning tool for these stones. This physical method allows cleaning to be achieved in a selective, gradual, and respectful way with the environment and the workers’ health. A sustainable cleaning method is therefore possible. In addition to the innovative use of lasers to clean heritage polymineralic stones, this Galician research group made progress in this area with the simultaneous application of wavelengths (infrared-1064 nm and ultraviolet-355 nm) and the sequential combination of laser with chemical and mechanical cleaning procedures. These strategies have made it possible to reach high levels of extraction and reduce side effects thanks to the reduction of applied fluence levels.
Keywords:
Downloads
Article Details
References
Agulló-Rueda, F., 2010. Espectroscopía Raman. En Egido, M. D. y Calderón, T. (eds.). La Ciencia y el Arte. Ciencias experimentales y conservación del Patrimonio Histórico. 117-125. IPHE, Ministerio de Cultura de España, Madrid. http://www.calameo.com/read/00007533584c6b757a9fb
Asmus, J.F., Murphy, C.G., Munk,W.H., 1974. En: Wuerker, R.F. (Ed.), Studies on the Interaction of Laser Radiation With Art Artifacts. Annu. Tech. Symp., International Society for Optics and Photonics, pp. 19–30 http://dx.doi.org/10.1117/12.953831
Barreiro, P., González, P., Pozo-Antonio, J.S., 2019. IR irradiation to remove a sub-aerial biofilm from granitic stones using two different laser systems: An Nd: YAG (1064 nm) and an Er:YAG (2940 nm). Science of the Total Environment 688, 632-641. https://doi.org/10.1016/j.scitotenv.2019.06.306
Barreiro, P., Andreotti, A., Colombini, M. P, González, P., Pozo-Antonio, J.S.. 2020. Influence of the Laser Wavelength on Harmful Effects on Granite Due to Biofilm Removal. Coatings 10(3), 196. https://doi.org/10.3390/coatings10030196
Bromblet, P., Laboure, M., Orial, G., 2003. Diversity of the cleaning procedures including laser for the restoration of carved portals in France over the last 10 years. Journal of Cultural Heritage 4, 17S–26S. https://doi.org/10.1016/S1296-2074(02)01222-0
Chapoulie, R., Cazenave, S., Duttine,M., 2008. Laser cleaning of historical limestone buildings in Bordeaux appraisal using cathodoluminescence and electron paramagnetic resonance. Environmental Science and Pollutuin Research 15, 237–243. https://doi.org/10.1065/espr2007.07.436
Cooper, M.I., Emmony, D.C., Larson, J., 1995. Characterization of laser cleaning of limestone. Optics & Laser Technology 27, 69–73. http://dx.doi.org/10.1016/0030-3992(95)93962-Q
Domingo, C., 2011. Técnicas de espectroscopía Raman aplicadas en conservación. En Egido, M. D. y Juanes, D. (eds.). La Ciencia y el Arte III. Madrid: IPCE, MCU.
ESCRBBCCG web, acceso el 24 de diciembre del 2022. https://escolaconservacion.gal/?lang=es
Fiorucci, M.P., López, A.J., Ramil, A., Pozo S., Rivas, T., 2013. Optimization of graffiti removal on natural stone by means of high repetition rate UV laser. Applied Surface Science 278, 268–272. https://doi.org/10.1016/j.apsusc.2012.10.092
Fotakis, C., Anglos, D., Zafiropoulos, V., Georgiou, S., Tornari, V., 2006. Lasers in the Preservation of Cultural Heritage: Principles and Applications. London: Taylor & Francis.
GESSMin web, acceso el 24 diciembre del 2022. http://gessmin.webs.uvigo.es/gl/
Gomes, V., Dionisio, A., Pozo-Antonio, J.S., Rivas, T., Ramil., 2018. Mechanical and laser cleaning of spray graffiti paints on a granite subjected to a SO2-rich atmosphere. Construction and building materials 188, 621–632. https://doi.org/10.1016/j.conbuildmat.2018.08.130
LACONA web, acceso 24 de diciembre 2022. http://www.lacona13.eu/
LAIL web, acceso el 24 diciembre del 2022. https://cit.udc.es/grupos-investigacion-cit/laboratorio-aplicaciones-industriales-laser/
López, A.J., Lamas, J., Pozo-Antonio, J.S., Rivas, T., Ramil, A., 2020. Development of processing strategies for 3D controlled laser ablation: Application to the cleaning of stonework surfaces. Optics and Lasers in Engineering 126, 105897. https://doi.org/10.1016/j.optlaseng.2019.105897
Maravelaki-Kalaitzaki, P., Anglos, D., Kilikoglou, V., Zafiropulos, V., 2001. Compositional characterization of encrustation on marble with laser induced breakdown spectroscopy. Spectrochimica Acta Part B: Atomic Spectroscopy 56, 887–903. http://dx.doi.org/10.1016/S0584-8547(01)00226-9
Moropoulou, A., Kefalonitou, S., 2002. Efficiency and counter effects of cleaning treatment on limestone surfaces - investigation on the Corfu Venetian Fortress. Building and Environment 37, 1181–1191. http://dx.doi.org/10.1016/S0360-1323(01)00059-2
Nello Carrara web, acceso 24 de diciembre 2022. http://www.ifac.cnr.it/
Osticioli, I.,Mascalchi, M., Pinna, D., Siano, S., 2014. Removal of Verrucaria nigrescens from Carrara marble artefacts using Nd:YAG lasers: comparison among different pulse durations and wavelengths. Applied Physics A - Materials Science & Processing 118, 1517–1526. http://dx.doi.org/10.1007/s00339-014-8933-y
Oujja, M., Rebollar, E., Castillejo, M., Domingo, C., Cirujano, C., Guerra-Librero, F., 2005. Laser cleaning of terracotta decorations of the portal of Palos of the Cathedral of Seville. Journal of Cultural Heritage 6, 321–327. http://dx.doi.org/10.1016/j.culher.2005.05.001
PHS web, acceso 24 de diciembre 2022. https://www.iesl.forth.gr/en/research/photonics-heritage-science
Potgieter-Vermaak, S.S., Godoi, R.H.M., Van Grieken, R., Potgieter, J.H., Oujja, M., Castillejo, M., 2005. Micro-structural characterization of black crust and laser cleaning of building stones by micro-Raman and SEM techniques. Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy 61, 2460–2467. http://dx.doi.org/10.1016/j.saa.2004.09.010
Pouli, P., Fotakis, C., Hermosin, B., Saiz-Jimenez, C., Domingo, C., Oujja, M., Castillejo, M., 2008. The laser-induced discoloration of stonework; a comparative study on its origins and remedies. Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy 71, 932–945. http://dx.doi.org/10.1016/j.saa.2008.02.031
Pouli, P., Oujja, M., Castillejo, M., 2011. Practical issues in laser cleaning of stone and painted artefacts: optimisation procedures and side effects. Applied Physics A - Materials Science & Processing 106, 447–464. http://dx.doi.org/10.1007/s00339-011-6696-2
Pozo, S., Barreiro, P., Rivas, T., Gonzalez, P., Fiorucci, M.P., 2014. Effectiveness and harmful effects of sulphated black crust removal from granite using Nd:YAG nanosecond pulsed laser. Applied Surface Science 302, 309-313. https://doi.org/10.1016/j.apsusc.2013.10.129
Pozo-Antonio, J.S., Fiorucci, M.P. Ramil, A., López-Díaz, AJ., Rivas, T., 2015. Evaluation of the effectiveness of laser crust removal on granites by means of hyperspectral imaging techniques. Applied Surface Science 347, 832–838. https://doi.org/10.1016/j.apsusc.2015.04.182
Pozo-Antonio, J.S., Rivas, T., Fiorucci, M.P., López A.J., Ramil, A., 2016a. Effectiveness and harmfulness evaluation of graffiti cleaning by mechanical, chemical and laser procedures on granite. Microchemical Journal 125, 1–9. https://doi.org/10.1016/j.microc.2015.10.040
Pozo-Antonio, J.S., Ramil, A., Fiorucci, M.P., López, A.J., Rivas, T., 2016b. The use of hyperspectral imaging technique to detect the most suitable graffiti-cleaning procedure. Color Research and Application. https://doi.org/10.1002/col.22032
Pozo-Antonio, J.S., Fiorucci, M. P., Rivas, T., López, A.J., Ramil, A., Barral, D., 2016c. Suitability of hyperspectral imaging technique to evaluate the effectiveness of the cleaning of a crustose lichen developed on granite. Applied Physics A -materials science & processing, 122, 100. https://doi.org/10.1007/s00339-016-9634-5
Pozo-Antonio, J.S., Ramil, A, Rivas, T., López, A.J., Fiorucci, M.P., 2016d. Effectiveness of chemical, mechanical and laser cleaning methods of sulphated black crusts developed on granite. Construction and Building Materials 112, 682–690. https://doi.org/10.1016/j.conbuildmat.2016.02.195
Pozo-Antonio, J.S., Fiorucci,M.P., Ramil, A., Rivas, T., López, A.J., 2016e. Hyperspectral imaging as a non destructive technique to control the laser cleaning of graffiti on granite. Journal of nondestructive evaluation 35, 44. https://doi.org/10.1007/s10921-016-0361-9
Pozo-Antonio, J.S., Rivas, T., Fiorucci,M.P., Ramil, A., López, A.J., 2016f. Effectiveness of granite cleaning procedures in cultural heritage: a review. Science of the Total Environment 571, 1017–1028. https://doi.org/10.1016/j.scitotenv.2016.07.090
Pozo-Antonio, J.S., Papanikolaou, A., Melessanaki, K., Rivas, T., Pouli, P., 2018. Laser assisted removal of graffiti from granite: advantages of the simultaneous combination of two wavelengths. Coatings 8, 4 124. https://doi.org/10.3390/coatings8040124
Pozo-Antonio, J.S., Papanikolaou, A., Philippidis, A., Melessanaki, K., Pouli, P., Rivas, T., 2019a. Cleaning of gypsum black crusts on granite using a dual wavelength Nd:YAG laser. Construction and Building Materials 226, 721–733. https://doi.org/10.1016/j.conbuildmat.2019.07.298
Pozo-Antonio, J.S., Barreiro, P., González, P., Paz-Bermúdez, G., 2019b. Nd:YAG and Er:YAG laser cleaning to remove Circinaria hoffmanniana (Lichenes, Ascomycota) from schist located in the Côa Valley Archaeological Park. International Biodeterioration and Biodegradation, 144, art. no. 104748. https://doi.org/10.1016/j.ibiod.2021.105276
Pozo-Antonio, J.S., Barreiro, P., Paz-Bermúdez, G., González, P., Batarda, A.P, 2021a. Effectiveness and durability of chemical-and laser-based cleanings of lichen mosaics on schists at archaeological sites. International Biodeterioration and Biodegradation 163, 105276. https://doi.org/10.1016/j.ibiod.2021.105276
Pozo-Antonio, J.S., Rivas, T., López de Silanes, M.E., Ramil A., López, A.J., 2021b. Dual combination of cleaning methods (scalpel, biocide, laser) to ensanche lichen removal from granite. International Biodeterioration and Biodegradation 168, 105373. https://doi.org/10.1016/j.ibiod.2021.105276
Pozo-Antonio, J.S., Antonio Fontán, N. 2021c. Aplicación de un láser Nd:YAG para retirar grafiti de la caliza Lioz: influencia de los parámetros láser (longitud de onda, fluencia y número de pulsos) y la composición del grafiti. Cadernos do Laboratorio Xeoloxico de Laxe 43, 17–40. https://doi.org/10.17979/cadlaxe.2021.43.0.8751
Ramil, A., Pozo-Antonio, J.S., Fiorucci, M. P., López, A.J., Rivas, T., 2017. Detection of the optimal laser fluence ranges to clean graffiti on silicates. Construction and Building Materials 148, 122–130. https://doi.org/10.1016/j.conbuildmat.2017.05.035
Ricci, C., Gambino, F., Nervo., M., Piccirillo, A., Scarcella, A., Zenucchini, F., Pozo-Antonio. J.S. 2020a. Developing New Cleaning Strategies of Cultural Heritage Stones: Are Synergistic Combinations of a Low-Toxic Solvent Ternary Mixtures Followed by Laser the Solution?. Coatings 10 (5), 466; https://doi.org/10.3390/coatings10050466
Ricci, C., Gambino, F., Nervo, M., Piccirillo, A., Scarcella, A., Zenucchini, F., Ramil. A., Pozo-Antonio, J.S., 2020b. Enhancement of graffiti removal from heritage stone by combining laser ablation and application of a solvent mixture. Construction and building materials 262, 119934. https://doi.org/10.1016/j.conbuildmat.2020.119934
Rivas, T., Pozo, S., Fiorucci, M.P., López, A.J., Ramil, A., 2012. Nd:YVO4 laser removal of graffiti from granite. Influence of paint and rock properties on cleaning efficacy. Applied Surface Science 263, 563–572. https://doi.org/10.1016/j.apsusc.2012.09.110
Rivas. T., Lopez, A.J., Ramil, A., Pozo, S., Fiorucci, P., López de Silanes, M.E., García, A., Vazquez de Aldana, J.R., Romero, C., Moreno, P., 2013. Comparative study of ornamental granite cleaning using femtosecond and nanosecond pulsed lasers. Applied Surface Science 278, 226–233. https://doi.org/10.1016/j.apsusc.2012.12.038
Rivas, T., Pozo-Antonio, J.S., López de Silanes, M.E., Ramil, A., López, A.J., 2018. Laser versus scalpel cleaning of crustose lichen on granite. Applied Surface Science 440, 467–476. https://doi.org/10.1016/j.apsusc.2018.01.167
Rivas, T., Pozo-Antonio, J.S., Ramil, A., López, A.J., 2020. Influence of the weathering rate on the response of granite to nanosecond UV laser irradiation. Science of the Total Environment 706, 135999. https://doi.org/10.1016/j.scitotenv.2019.135999
Sanz,M., Oujja,M., Ascaso, C., de los Ríos, A., Pérez-Ortega, S., Souza-Egipsy, V.,Wierzchos, J., Speranza,M., Cañamares,M.V., Castillejo, M., 2015. Infrared and ultraviolet laser removal of crustose lichens on dolomite heritage stone. Applied Surface Science 346, 248–255. https://dx.doi.org/10.1016/j.apsusc.2015.04.013
Siano, S., Agresti, J., Cacciari, I., Ciofini, D., Mascalchi, M., Osticioli, I., Mencaglia, A.A., 2012. Laser cleaning in conservation of stone, metal, and painted artifacts: state of the art and new insights on the use of the Nd:YAG lasers. Applied Physics A - Materials Science & Processing 106, 419–446. http://dx.doi.org/10.1007/s00339-011-6690-8
Tserevelakis, G.J., Pozo-Antonio, J.S., Siozos, P., Rivas, T., Pouli, P., Zacharakis, G., 2019. On-line photoacoustic monitoring of laser cleaning on stone: evaluation of cleaning effectiveness and detection of potential damage to the substrate. Journal of Cultural heritage 35, 108–115. https://doi.org/10.1016/j.culher.2018.05.014
Weeks, C., 1998. The 'Portail de la Mere Dieu' of Amiens Cathedral: Its polychromy and conservation. Studies in Conservation 43 (2), 101–108. https://doi.org/10.2307/1506646